REMOVAL OF VARIOUS METAL IONS IN WATER BY DIFFERENT PRE-TREATMENTS OF FLY ASH

Authors

  • Wen-Pei Low Department of Civil Engineering, Faculty of Engineering and Quantity Surveying, INTI INTERNATIONAL UNIVERSITY, MALAYSIA
  • Wong Wai Chun Department of Civil Engineering, Faculty of Engineering and Quantity Surveying, INTI INTERNATIONAL UNIVERSITY, MALAYSIA
  • Fung-Lung Chang Department of Civil Engineering, Faculty of Engineering and Quantity Surveying, INTI INTERNATIONAL UNIVERSITY, MALAYSIA
  • Hoong Pin Lee Department of Civil Engineering, Faculty of Engineering and Quantity Surveying, INTI INTERNATIONAL UNIVERSITY, MALAYSIA
  • Noorul Hudai Abdullah Neo Environmental Technology, Centre for Diploma Studies, UNIVERSITI TUN HUSSEIN ONN MALAYSIA
  • Santhana Krishnan Department of Civil and Environmental Engineering, Faculty of Engineering, PRINCE OF SONGKLA UNIVERSITY, THAILAND
  • Kian-Ghee Tiew School of Environmental Science and Engineering, GUANGDONG UNIVERSITY OF PETROCHEMICAL TECHNOLOGY, CHINA

DOI:

https://doi.org/10.21837/pm.v22i33.1536

Keywords:

fly ash, metal ions, water treatment, adsorption, water pollution

Abstract

Rapid urbanisation in Malaysia has accelerated water pollution in rivers and other water sources, causing irreversible harm to the ecosystem. In view of that, this study aimed to work on using fly ash to address certain heavy metal components (chromium (Cr), copper (Cu), nickel (Ni), and zinc (Zn)) present in polluted water. The experiment employed three batches of fly ash. Two batches were treated with sodium hydroxide (NaOH-FA) and hydrochloric acid (HCl-FA), whereas one batch was left untreated (UFA). The three batches of adsorbents were examined by using a jar test after solutions containing 100 mg/L of Cr, Cu, Ni, and Zn ions were made. The results of various contact periods demonstrated that the fly ash had variable capacities for metal ion adsorption. The maximum adsorption of UFA was 79.958%(Cr), 80.814%(Cu), 81.580%(Ni), and 82.742%(Zn) while HCl-FA was adsorbing 77.148%(Cr), 82.546%(Cu), 78.896%(Ni), and 78.248%(Zn). NaOH-FA in this study was found to adsorb 80.828%(Cr), 79.230%(Cu), 81.692%(Ni), and 77.394%(Zn). Further to this, it was revealed that the Temkin Isotherm model was best fitted with the highest R² values (> 0.98). The negative value of the slope, B indicated that the adsorption is an endothermic process which leans towards physical adsorption. In conclusion, this study demonstrated the successful application of fly ash in water or wastewater treatment of metal ions.

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References

Adewoye, L.T., Mustapha, S.I., Adeniyi, A.G., Tijani, J.O., Amoloye, M.A. & Ayinde, L.J. (2017). Optimization of nickel (ii) and chromium (iii) removal from contaminated water using sorghum bicolor. Nigerian Journal of Technology, 36(3), 960-972. DOI: https://doi.org/10.4314/njt.v36i3.41

Agarwal, S., Rajoria, P. & Rani, A. (2018). Adsorption of tannic acid from aqueous solution onto chitosan/NaOH/fly ash composites: Equilibrium, kinetics, thermodynamics and modelling. Journal of environmental chemical engineering, 6(1), 1486-1499. DOI: https://doi.org/10.1016/j.jece.2017.11.075

Alsaffar, M.S., Suhaimi, J.M. & Ahmad, K.N. (2019). Evaluation of heavy metals in surface water of major rivers in Penang, Malaysia. International Journal of Environmental Science, 6(5), 657-669.

Alterary, S.S. & Marei, N.H. (2021). Fly ash properties, characterization, and applications: A review. Journal of King Saud University-Science, 33(6), p.101536. DOI: https://doi.org/10.1016/j.jksus.2021.101536

Beddu, S., Zainoodin, M., Kamal, N.M., Mohamad, D., Nabihah, S. & Nazri, F.M. (2018). Material characterization of coal combustion product (cenosphere) generated from coal–fired power plant in Malaysia. In AIP Conference Proceedings, 2030 (1). AIP Publishing. DOI: https://doi.org/10.1063/1.5066900

Buema, G., Harja, M., Lupu, N., Chiriac, H., Forminte, L., Ciobanu, G., Bucur, D. & Bucur, R.D. (2021). Adsorption performance of modified fly ash for copper ion removal from aqueous solution. Water, 13(2), p.207. DOI: https://doi.org/10.3390/w13020207

Chen, X., Zhang, G., Li, J., & Ji, P. (2021). Possibility of removing Pb and Cd from polluted water by modified fly ash. Adsorption Science & Technology, 2021, 1-8. DOI: https://doi.org/10.1155/2021/1336638

Darmayanti, L., Notodarmodjo, S., Damanhuri, E. & Mukti, R.R. (2018). Removal of copper (II) ions in aqueous solutions by sorption onto alkali activated fly ash. In MATEC Web of Conferences, 147, EDP Sciences, p. 04007. DOI: https://doi.org/10.1051/matecconf/201814704007

De Maeijer, P.K., Craeye, B., Snellings, R., Kazemi-Kamyab, H., Loots, M., Janssens, K. & Nuyts, G. (2020). Effect of ultra-fine fly ash on concrete performance and durability. Construction and Building Materials, 263, p.120493. DOI: https://doi.org/10.1016/j.conbuildmat.2020.120493

Elmorsi, R.R., Abou-El-Sherbini, K.S., Shehab El-Dein, W.A. & Lotfy, H.R. (2022). Activated eco-waste of Posidonia oceanica rhizome as a potential adsorbent of methylene blue from saline water. Biomass Conversion and Biorefinery, 1-14. DOI: https://doi.org/10.1007/s13399-022-02709-5

Eteba, A., Bassyouni, M., & Saleh, M. (2021). Removal of hazardous organic pollutants using fly ash. Environ. Ecol. Res, 9, 196-203. DOI: https://doi.org/10.13189/eer.2021.090407

Ghazali, N., Muthusamy, K. & Wan Ahmad, S. (2019). Utilization of Fly Ash in Construction. IOP Conference Series: Materials Science and Engineering, 601, p. 012023. DOI: https://doi.org/10.1088/1757-899X/601/1/012023

Gjyli, S., Korpa, A., Teneqja, V., Siliqi, D. & Belviso, C. (2021). Siliceous fly ash utilization conditions for zeolite synthesis. Environmental Sciences Proceedings, 6(1), p.24. DOI: https://doi.org/10.3390/iecms2021-09359

Go, Y.W. and Yeom, S.H. (2019). Fabrication of a solid catalyst using coal fly ash and its utilization for producing biodiesel. Environmental Engineering Research, 24(2), 324-330. DOI: https://doi.org/10.4491/eer.2018.029

Goi, C.L. (2020). The river water quality before and during the Movement Control Order (MCO) in Malaysia. Case Studies in Chemical and Environmental Engineering, 2, p.100027. DOI: https://doi.org/10.1016/j.cscee.2020.100027

Habibullah, N., Sahrir, S., & Ponrahono, Z. (2023). Integrating Rainwater Harvesting And Greywater Recycling To Increase Water Efficiency In Office Buildings. PLANNING MALAYSIA, 21(5), 253-266. DOI: https://doi.org/10.21837/pm.v21i29.1369

Li, J., Gan, J., Wang, G., Chen, Z. & Gong, Y. (2016). Research on adsorbent using modified fly ash for campus domestic sewage treatment. In MATEC Web of Conferences, 67, EDP Sciences, p. 07003. DOI: https://doi.org/10.1051/matecconf/20166707003

Mardi, N.H., Ean, L.W., Malek, M.A., Chua, K.H. & Ahmed, A.N. (2023). Operational blue water footprint and water deficit assessment of coal-fired power plants: case study in Malaysia. Environmental Sciences Europe, 35(1), 1-15. DOI: https://doi.org/10.1186/s12302-023-00759-8

Naiya, T.K. & Das, S.K. (2016). Removal of Cr (VI) from aqueous solution using fly ash of different sources. Desalination and Water Treatment, 57(13), 5800-5809. DOI: https://doi.org/10.1080/19443994.2014.1003611

Nandiyanto, A.B.D., Girsang, G.C.S. & Rizkia, R.S. (2022). Isotherm adsorption characteristics of 63-um calcium carbonate particles prepared from eggshells waste. Journal of Engineering Science and Technology, 17 (5), 3203-3210.

Nguyen, D. H. (2020). Itai-Itai disease: the role of mining in the degradation of Japanese society and public health (Doctoral dissertation, The Ohio State University).

Nguyen, T. C., Tran, T. D. M., Dao, V. B., Vu, Q. T., Nguyen, T. D., & Thai, H. (2020). Using modified fly ash for removal of heavy metal ions from aqueous solution. Journal of Chemistry, 2020, 1-11. DOI: https://doi.org/10.1155/2020/8428473

Ohale, P.E., Onu, C.E., Ohale, N.J. & Oba, S.N. (2020). Adsorptive kinetics, isotherm and thermodynamic analysis of fishpond effluent coagulation using chitin derived coagulant from waste Brachyura shell. Chemical Engineering Journal Advances, 4, p.100036. DOI: https://doi.org/10.1016/j.ceja.2020.100036

Othman, F., Uddin Chowdhury, M.S., Wan Jaafar, W.Z., Mohammad Faresh, E.M. & Shirazi, S.M. (2018). Assessing Risk and Sources of Heavy Metals in a Tropical River Basin: A Case Study of the Selangor River, Malaysia. Polish Journal of Environmental Studies, 27(4), 1659-1671. DOI: https://doi.org/10.15244/pjoes/76309

Owino, E.K., Shikuku, V.O., Nyairo, W.N., Kowenje, C.O. & Otieno, B. (2023). Valorization of solid waste incinerator fly ash by geopolymer production for removal of anionic bromocresol green dye from water: Kinetics, Isotherms and Thermodynamics studies. Sustainable Chemistry for the Environment, p.100026. DOI: https://doi.org/10.1016/j.scenv.2023.100026

Potgieter, J.H., Pardesi, C. & Pearson, S. (2021). A kinetic and thermodynamic investigation into the removal of methyl orange from wastewater utilizing fly ash in different process configurations. Environmental Geochemistry and Health, 43, 2539-2550. DOI: https://doi.org/10.1007/s10653-020-00567-6

Qasem, N. A., Mohammed, R. H., & Lawal, D. U. (2021). Removal of heavy metal ions from wastewater: A comprehensive and critical review. Npj Clean Water, 4(1), 36. DOI: https://doi.org/10.1038/s41545-021-00127-0

Ramesh, S., Sudarsan, J.S. & Jothilingam, M. (2016). Low cost natural adsorbent technology for water treatment. Rasayan Journal of Chemistry, 9(3), 325-330.

Ranasinghe, R. A. J. C., Hansima, M. A. C. K., & Nanayakkara, K. G. N. (2022). Adsorptive removal of fluoride from water by chemically modified coal fly ash: Synthesis, characterization, kinetics, and mechanisms. Groundwater for Sustainable Development, 16, 100699. DOI: https://doi.org/10.1016/j.gsd.2021.100699

Rondón, W., Freire, D., de Benzo, Z., Sifontes, A.B., González, Y., Valero, M. & Brito, J.L. (2013). Application of 3A zeolite prepared from Venezuelan kaolin for removal of Pb (II) from wastewater and its determination by flame atomic absorption spectrometry. American Journal of Analytical Chemistry, 4(10), 584-593. DOI: https://doi.org/10.4236/ajac.2013.410069

Salleh, H., Ying, C. K., Hanid, M., Samad, Z. A., Sabli, N. A. M., & Khuzzan, S. M. S. (2022). Development Of Guidance For The Adoption Of Circular Economy In Construction And Demolition Waste Management. PLANNING MALAYSIA, 20 (5), 415-427. DOI: https://doi.org/10.21837/pm.v20i24.1216

Santi, L.P., Goenadi, D.H., Kalbuadi, D.N. & Sari, I.P. (2021). Alkaline pre-treatment of coal fly ash as bio-silica fertilizer. Journal of Minerals and Materials Characterization and Engineering, 9(02), p.180. DOI: https://doi.org/10.4236/jmmce.2021.92013

Sylwan, I. & Thorin, E. (2021). Removal of heavy metals during primary treatment of municipal wastewater and possibilities of enhanced removal: A review. Water, 13(08), p.1121. DOI: https://doi.org/10.3390/w13081121

Tan, Y.H., Chai, M.K., Na, J.Y. & Wong, L.S. (2023). Microalgal Growth and Nutrient Removal Efficiency in Non-Sterilised Primary Domestic Wastewater. Sustainability, 15(8), p.6601. DOI: https://doi.org/10.3390/su15086601

Feary, J., & Cullinan, P. (2019). Heavy Metals. Reference Module in Biomedical Sciences [Internet]; Elsevier: Amsterdam, The Netherlands.

Wadhawan, S., Jain, A., Nayyar, J. & Mehta, S.K. (2020). Role of nanomaterials as adsorbents in heavy metal ion removal from waste water: A review. Journal of Water Process Engineering, 33, p.101038. DOI: https://doi.org/10.1016/j.jwpe.2019.101038

World Health Organization, WHO (2023). Humanitarian emergencies - Water Sanitation and Health. Health risks: Drinking-water and sanitation. Retrieved from: https://www.who.int/teams/environment-climate-change-and-health/water-sanitation-and-health/environmental-health-in-emergencies/humanitarian-emergencies

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Published

2024-08-26

How to Cite

Low, W.-P., Chun, W. W., Chang, F.-L., Lee, H. P., Abdullah, N. H., Krishnan, S., & Tiew, K.-G. (2024). REMOVAL OF VARIOUS METAL IONS IN WATER BY DIFFERENT PRE-TREATMENTS OF FLY ASH. PLANNING MALAYSIA, 22(33). https://doi.org/10.21837/pm.v22i33.1536